A New Type of Reductive Cleavage of Disulfide in Quadruply ortho-Substituted Diphenyl Disulfide by Neighboring Thiolate Anion

Synthesis of Zinc Dimethyldithiocarbamate by Reductive Disulfide Bond Cleavage of Tetramethylthiuram Disulfide in Presence of Zn2+

The zinc(II) complex [Zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = N,N-dimethyldithiocarbamate; thiram = N,N-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. Surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with Zn2+ in methanolic media to give the [Z...

synthesis of zinc dimethyldithiocarbamate by reductive disulfide bond cleavage of tetramethylthiuram disulfide in presence of zn2+

the zinc(ii) complex [zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = n,n-dimethyldithiocarbamate; thiram = n,n-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with zn2+ in methanolic media to give the [z...

synthesis of zinc dimethyldithiocarbamate by reductive disulfide bond cleavage of tetramethylthiuram disulfide in presence of zn2+

the zinc(ii) complex [zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = n,n-dimethyldithiocarbamate; thiram = n,n-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with zn2+ in methanolic media to give the [z...

Reductive cleavage of disulfide bridges in ribonuclease.

Production of Iron Disulfide Nanoparticles by Hydrothermal Process

In this research, a single-stage low-temperature hydrothermal synthesis route was successfully developed for preparation of Iron Disulfide. The prepared powder was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). These analyses showed that nanoparticles were well crystallized, pyrite was the main product and the shape of crystals was nanorod. Also, the influences...